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<article article-type="research-article" dtd-version="1.3" xml:lang="ru">
  <front xmlns:xlink="http://www.w3.org/1999/xlink">
    <journal-meta>
      <journal-id journal-id-type="elibrary">https://www.elibrary.ru/title_about_new.asp?i</journal-id>
      <journal-title-group>
        <journal-title>Materials physics and mechanics</journal-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Механика и физика материалов</trans-title>
        </trans-title-group>
      </journal-title-group>
      <issn pub-type="epub">1605-8119</issn>
    </journal-meta>
    <article-meta xmlns:xlink="http://www.w3.org/1999/xlink">
      <article-id pub-id-type="publisher-id">9</article-id>
      <article-id pub-id-type="doi">10.18720/MPM.4012018_9</article-id>
      <title-group>
        <article-title>Fullerene molecule as a nanosize quantum system</article-title>
        <trans-title-group xml:lang="ru">
          <trans-title>Fullerene molecule as a nanosize quantum system</trans-title>
        </trans-title-group>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <name>
            <surname>Krasinkova</surname>
          </name>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
      </contrib-group>
      <aff id="aff1">Ioffe Institute</aff>
      <pub-date publication-format="electronic" date-type="pub" iso-8601-date="2018-10-20">
        <day>20</day>
        <month>10</month>
        <year>2018</year>
      </pub-date>
      <volume>40</volume>
      <issue>1</issue>
      <fpage>71</fpage>
      <lpage>77</lpage>
      <self-uri xmlns:xlink="http://www.w3.org/1999/xlink" content-type="pdf" xlink:href="https://mpm.spbstu.ru/userfiles/files/MPM140_09_krasinkova.pdf"/>
      <abstract xml:lang="en">
        <p>It is shown that a strong Coulomb and exchange interactions between π electrons in a fullerene molecule lead to the localization of these electrons, quantization of their energies, and a highly correlated state manifesting itself in the formation of electron crystals. In this approximation the fullerene molecule is a nanosize quantum system consisting of a positively charged rolled-up carbon backbone surrounded by three electron crystals: (i) two crystals formed by π electrons in the 2 pz state that participate in the π bond formation through the resonance of structures and are located on the convex and concave sides of the molecule, and (ii) the crystal formed by pairs of π* electrons excited into the 2pz 3s state and participating in the formation of nonresonant π* bonds. The chemical activity and physical properties of such a system are determined by the crystal formed by electron pairs.</p>
      </abstract>
      <kwd-group xml:lang="en">
        <kwd>fullerenes</kwd>
        <kwd>highly correlated electron state</kwd>
        <kwd>electron crystals</kwd>
        <kwd>nanosize quantum system</kwd>
      </kwd-group>
    </article-meta>
  </front>
</article>
